We consider the Maxwell-Schrödinger equations in the Coulomb gauge describing the interaction of extended fermions with their self-generated electromagnetic field. They heuristically emerge as mean-field equations from non-relativistic quantum electrodynamics in a mean-field limit of many fermions. In the semiclassical regime, we establish the convergence of the Maxwell-Schrödinger equations for extended charges towards the non-relativistic Vlasov-Maxwell dynamics and provide explicit estimates on the accuracy of the approximation. To this end, we build a well-posedness and regularity theory for the Maxwell-Schrödinger equations and for the Vlasov-Maxwell system for extended charges.